Writer: Jun Chen, Wei Wu, Chuan Chen, Sanxiong He.

Journal: Journal of Applied Polymer Science, 2010,115(1)：588–598

Abstract: The elastomer toughening of PA66/PA6 nano-composites prepared from the organic modified montmorillonite (OMMT) was examined as a means of balancing stiffness/strength versus toughness/ductility. Several different formulations varying in OMMT content were made by mixing of PA6 and OMMT as a master-batch and then blending it with PA66 and different elastomers in a twin screw extruder. In this sequence, the OMMT layers were well exfoliated in the nylon alloy matrix. The introduction of silicate layers with PA6 induced the appearance of the crystal phase in the nano-composites, which is unstable and seldom appears in PA66 at room temperature and it further affected the morphology and dispersion of rubber phase resulting in much smaller rubber particles. The incorporation of POE-g-MA particles toughened the nano-composites markedly, but the tensile modulus and strength were both reduced. Conversely, the use of OMMT increased the modulus but decreased the fracture toughness. The nano-composites exhibited balanced stiffness and toughness.